On the basis of standard electrode potential values $(E^{\circ})$, suggest which of the following reactions would take place spontaneously? Given: $E^{\circ}_{Zn^{2+}/Zn} = -0.76 \ V$, $E^{\circ}_{Cu^{2+}/Cu} = +0.34 \ V$, $E^{\circ}_{Mg^{2+}/Mg} = -2.37 \ V$, $E^{\circ}_{Fe^{2+}/Fe} = -0.44 \ V$, $E^{\circ}_{Br_{2}/Br^{-}} = +1.09 \ V$, $E^{\circ}_{Cl_{2}/Cl^{-}} = +1.36 \ V$, $E^{\circ}_{Cd^{2+}/Cd} = -0.40 \ V$.
- A$Cu + Zn^{2+} \rightarrow Cu^{2+} + Zn$
- B$Mg + Fe^{2+} \rightarrow Mg^{2+} + Fe$
- C$Br_{2} + 2Cl^{-} \rightarrow Cl_{2} + 2Br^{-}$
- D$Fe + Cd^{2+} \rightarrow Cd + Fe^{2+}$
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At $298 \, K$, the standard Gibbs free energy of formation for $H_2O_{(l)}$, $CO_{2(g)}$, and $C_5H_{12(g)}$ are $-237.2$, $-394.4$, and $-8.2 \, kJ \, mol^{-1}$ respectively. What is the potential of a pentane-oxygen fuel cell in $V$?
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View SolutionAll the energy released from the reaction $X \rightarrow Y, \Delta_{r}G^0 = -193 \ kJ \ mol^{-1}$ is used for oxidizing $M^{+}$ as $M^{+} \rightarrow M^{3+} + 2e^-, E^0 = -0.25 \ V$. Under standard conditions,the number of moles of $M^{+}$ oxidized when one mole of $X$ is converted to $Y$ is $\left[F = 96500 \ C \ mol^{-1}\right]$.
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View SolutionConsider the following cell reaction:
$Cd_{(s)} + Hg_{2}SO_{4(s)} + \frac{9}{5}H_{2}O_{(l)} \rightleftharpoons CdSO_{4} \cdot \frac{9}{5}H_{2}O_{(s)} + 2Hg_{(l)}$
The value of $E_{\text{cell}}^{0}$ is $4.315 \ V$ at $25^{\circ}C$. If $\Delta H^{\circ} = -825.2 \ kJ \ mol^{-1}$,the standard entropy change $\Delta S^{\circ}$ in $J \ K^{-1} \ mol^{-1}$ is ........ . (Nearest integer) [Given: Faraday constant $= 96487 \ C \ mol^{-1}$]
$Cd_{(s)} + Hg_{2}SO_{4(s)} + \frac{9}{5}H_{2}O_{(l)} \rightleftharpoons CdSO_{4} \cdot \frac{9}{5}H_{2}O_{(s)} + 2Hg_{(l)}$
The value of $E_{\text{cell}}^{0}$ is $4.315 \ V$ at $25^{\circ}C$. If $\Delta H^{\circ} = -825.2 \ kJ \ mol^{-1}$,the standard entropy change $\Delta S^{\circ}$ in $J \ K^{-1} \ mol^{-1}$ is ........ . (Nearest integer) [Given: Faraday constant $= 96487 \ C \ mol^{-1}$]
$A$ battery is made from $Cr$ and $Na_2Cr_2O_7$. When this battery discharges according to the reaction $Na_2Cr_2O_7 + Cr + H^{+} \rightarrow Cr^{3+} + H_2O + Na^{+}$,the chemical equation is unbalanced. If $1 \ F$ (Faraday) of electricity is passed during the charging of the battery,what is the number of moles of $Cr^{3+}$ removed from the solution (in $/3$)?
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View SolutionThe number of correct statements from the following is :
$A.$ $E_{cell}$ is an intensive parameter.
$B.$ $A$ negative $E^{\Theta}$ means that the redox couple is a stronger reducing agent than the $H^{+}/H_2$ couple.
$C.$ The amount of electricity required for oxidation or reduction depends on the stoichiometry of the electrode reaction.
$D.$ The amount of chemical reaction which occurs at any electrode during electrolysis by a current is proportional to the quantity of electricity passed through the electrolyte.
$A.$ $E_{cell}$ is an intensive parameter.
$B.$ $A$ negative $E^{\Theta}$ means that the redox couple is a stronger reducing agent than the $H^{+}/H_2$ couple.
$C.$ The amount of electricity required for oxidation or reduction depends on the stoichiometry of the electrode reaction.
$D.$ The amount of chemical reaction which occurs at any electrode during electrolysis by a current is proportional to the quantity of electricity passed through the electrolyte.
DifficultJEE MAIN 2023
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